Photoinduced post-modification of graphitic carbon nitride-embedded hydrogels: synthesis of 'hydrophobic hydrogels' and pore substructuring

• Cansu Esen and
• Baris Kumru

Beilstein J. Org. Chem. 2021, 17, 1323–1334, doi:10.3762/bjoc.17.92

• of this study, which is divided into two parts, the hydrogel denoted as HGCM was utilized as the main substrate for both sections. To prepare HGCM, firstly graphitic carbon nitride was synthesized from the thermal treatment of a cyanuric acid–melamine supramolecular complex (CM) [42]. The resulting

• isothiocyanate conjugate (FITC-Albumin, Sigma-Aldrich), calcium chloride (CaCl2, 97%, Alfa Aesar), cyanuric acid (98%, Sigma-Aldrich), fluoresceinisothiocyanat-dextran (FITC–Dextran, 10.000 Mw), hydrochloric acid (HCl, 37%, Sigma-Aldrich), hydrochloric acid (1 M solution, Sigma-Aldrich), hydrogen peroxide (30

• , 95%, Sigma-Aldrich), sodium chloride (NaCl, 99%, Sigma-Aldrich), sodium hydroxide (1 M solution, Sigma-Aldrich). DMA, PEGDMA, PEGMEMA and were passed through basic alumina column prior to use. Synthesis of g-CN: g-CN was synthesized from cyanuric acid–melamine supramolecular complex as reported in

Heterogeneous photocatalysis in flow chemical reactors

• Christopher G. Thomson,
• Ai-Lan Lee and
• Filipe Vilela

Beilstein J. Org. Chem. 2020, 16, 1495–1549, doi:10.3762/bjoc.16.125

Mechanistic studies of an L-proline-catalyzed pyridazine formation involving a Diels–Alder reaction with inverse electron demand

• Anne Schnell,
• J. Alexander Willms,
• S. Nozinovic and
• Marianne Engeser

Beilstein J. Org. Chem. 2019, 15, 30–43, doi:10.3762/bjoc.15.3

• , 0.31 mmol, 1 equiv) and TBCA (tribromoisocyanuric acid, 336 mg, 0.92 mmol, 3 equiv) were refluxed in 3 mL ethyl acetate for six hours. The precipitated cyanuric acid was filtered off over Celite®. The solvent was evaporated and 102 mg of a pink raw product was obtained. The raw product was purified via

• , ingredients see below) in 186 mL deionized water was added dropwise to a 0 °C cold stirred solution of cyanuric acid (2.00 g, 15.50 mmol, 1 equiv), sodium hydroxide (1.86 g, 46.49 mmol, 3 equiv), sodium carbonate (2.46 g, 23.24 mmol, 1.5 equiv) and potassium bromide (5.53 g, 46.49 mmol, 3 equiv) in 223 mL

Mannich base-connected syntheses mediated by ortho-quinone methides

• Petra Barta,
• Ferenc Fülöp and
• István Szatmári

Beilstein J. Org. Chem. 2018, 14, 560–575, doi:10.3762/bjoc.14.43

• ·5PW12O40 (CuPW); [42] or wet cyanuric acid (wet-TCT) [43] was also tested. These methods suffer from a number of drawbacks, such as strong acidic media, high temperature, and prolonged reactions. Furthermore, the yields are often not satisfactory. To eliminate the disadvantages of previous strategies

Strategies toward protecting group-free glycosylation through selective activation of the anomeric center

• A. Michael Downey and
• Michal Hocek

Beilstein J. Org. Chem. 2017, 13, 1239–1279, doi:10.3762/bjoc.13.123

• perfect stereoselectivity (Scheme 30). Glycosylation of the resulting DBT-β-glycosides was carried out in various alcohols (selected examples shown in Table 7) under Pd/C-catalyzed hydrogenolysis conditions to liberate the desired 1,2-cis glycoside and cyanuric acid. The reductant was either H2 (non

Mild and efficient cyanuric chloride catalyzed Pictet–Spengler reaction

• Ashish Sharma,
• Mrityunjay Singh,
• Nitya Nand Rai and
• Devesh Sawant

Beilstein J. Org. Chem. 2013, 9, 1235–1242, doi:10.3762/bjoc.9.140

• in the literature that TCT reacts with the incipient moisture and produces three moles of HCl and cyanuric acid as a byproduct [46]. The latter can be removed by a simple aqueous workup. Interestingly, this reagent has not been explored for the Pictet–Spengler reaction yet. Here we report the use of

• –Spengler reaction catalyzed by cyanuric acid. Both conventional and modified Pictet–Spengler substrates reacted equally well with electron-donating and electron-withdrawing aldehydes. TCT proved effective in catalyzing the 6-endo cyclization of aldehydes such as salicylaldehyde and 4

A general and facile one-pot process of isothiocyanates from amines under aqueous conditions

• Nan Sun,
• Bin Li,
• Jianping Shao,
• Weimin Mo,
• Baoxiang Hu,
• Zhenlu Shen and
• Xinquan Hu

Beilstein J. Org. Chem. 2012, 8, 61–70, doi:10.3762/bjoc.8.6

• generation of a dithiocarbamate salt from the amine substrate by reacting with CS2 followed by elimination to form the isothiocyanate product with cyanuric acid as the desulfurylation reagent. The choice of solvent is of decisive importance for the successful formation of the dithiocarbamate salt

• particularly for highly electron-deficient substrates. This novel and economical method is suitable for scale-up activities. Keywords: aqueous conditions; cyanuric acid; isothiocyanates; one-pot process; organic synthesis; primary amines; Introduction Isothiocyanates are a class of heteroallenic compounds

A hydrogen- bonded channel structure formed by a complex of uracil and melamine

• Reji Thomas and
• G. U. Kulkarni

Beilstein J. Org. Chem. 2007, 3, No. 17, doi:10.1186/1860-5397-3-17

• investigated. The structure involves hydrogen bonded layers with apertures stacked along the a and b directions giving rise to channels, unlike the complex of cyanuric acid with melamine. Background Hydrogen bonded organic structures have emerged to become an important area of research because of the wide

• variety of fascinating structural features as well as properties exhibited by them. Of the many interesting hydrogen bonded systems, those formed by cyanuric acid and melamine are specially interesting. Thus, cyanuric acid forms hydrogen bonded adducts with melamine, [1] 4,4'-bipyridyl [2] and 4,4

• '-bipyridylethene. [3] The last two involve layered structures, but that with melamine is fascinating and involves a rosette type structure wherein each molecule of cyanuric acid and melamine forms three hydrogen bonds on either side. Such a structure of the 1:1 molecular complex between cyanuric acid and melamine